Crystal structures of 1-benzenesulfonyl-2-methyl-3-(4-nitrobenzoyl)-2,3-dihydro-1H-indole and 1-benzenesulfonyl-2-methyl-3-[(thiophen-2-yl)carbonyl]-2,3-dihydro-1H-indole

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Crystal structures of 1-benzene­sulfon­yl-2-methyl-3-(4-nitro­benzoyl)-2,3-di­hydro-1H-indole and 1-benzene­sulfon­yl-2-methyl-3-[(thio­phen-2-yl)carbon­yl]-2,3-di­hydro-1H-indole

In the title indole derivatives, C22H16N2O5S, (I) and C20H15NO3S2, (II), the sulfonyl-bound phenyl rings are almost orthogonal to the indole ring system, subtending dihedral angles of 88.33 (10) and 87.58 (16)°, respectively. In both compounds, the sulfonyl S atom has a distorted tetra-hedral geometry [O-S-O = 119.98 (9) and N-S-C = 104.01 (8)° for compound (I) and O-S-O = 120.08 (18) and N-S-C...

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2-(4-Fluoro­phen­yl)-3-methyl-1H-indole

The indole N-H hydrogen in the title compound, C(15)H(12)FN, does not display classical hydrogen bonding. Rather it forms an interaction with the π system of an adjacent indole, resulting in weakly inter-acting chains along the [001] direction.

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3-(2-Methyl-2-nitro­prop­yl)-1H-indole

In the title compound, C(12)H(14)N(2)O(2), the indole ring is essentially planar, with an r.m.s. deviation of 0.0136 Å. In the crystal, pairs of N-H⋯O hydrogen bonds link the mol-ecules into inversion dimers..

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1-(4-Meth­oxy­phen­yl)-2-methyl-1H-indole-3-carbonitrile

In the title compound, C(17)H(14)N(2)O, the dihedral angle between the indole ring system and the benzene ring is 58.41 (4)°. The crystal packing features π-π stacking [shortest centroid-centroid separation = 3.8040 (9) Å] and C-H⋯π inter-actions.

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1-(4-Bromo­phen­yl)-2-methyl-1H-indole-3-carbonitrile

In the title compound, C(16)H(11)BrN(2), the dihedral angle between the indole ring system and the phenyl ring is 58.85 (11)°.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Crystallographic Communications

سال: 2017

ISSN: 2056-9890

DOI: 10.1107/s2056989017012804